ArticleJournal of the American Chemical Society2010
Synthesis of complex allylic esters via C-H oxidation vs C-C bond formation.
Article in Journal of the American Chemical Society, 2010. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
21 citing papers in PubMed, 107 citations in OpenAlex.
- General Modular and Convergent Approach to Diversely Functionalized Allylic Systems.Journal of the American Chemical Society · 2025Article
- General Regio- and Diastereoselective Allylic C-H Oxygenation of Internal Alkenes.Journal of the American Chemical Society · 2024Article
- Metal-free allylic C-H nitrogenation, oxygenation, and carbonation of alkenes by thianthrenation.Chemical science · 2022Article
- Aerobic Acyloxylation of Allylic C-H Bonds Initiated by a PdChemSusChem · 2019Article
- Operando Spectroscopic and Kinetic Characterization of Aerobic Allylic C-H Acetoxylation Catalyzed by Pd(OAc)Journal of the American Chemical Society · 2019Article
- Arylative Intramolecular Allylation of Ketones with 1,3-Enynes Enabled by Catalytic Alkenyl-to-Allyl 1,4-Rhodium(I) Migration.Angewandte Chemie (International ed. in English) · 2017Article
- Oxidation of Hindered Allylic C-H Bonds with Applications to the Functionalization of Complex Molecules.ACS catalysis · 2017Article
- Cross-dehydrogenative coupling for the intermolecular C-O bond formation.Beilstein journal of organic chemistry · 2015Review
- OPolyhedron · 2014Article
- Copper-catalyzed oxidative dehydrogenative carboxylation of unactivated alkanes to allylic esters via alkenes.Journal of the American Chemical Society · 2014Article
- Non-Directed Allylic C-H Acetoxylation in the Presence of Lewis Basic Heterocycles.Chemical science · 2014Article
- A C-H oxidation approach for streamlining synthesis of chiral polyoxygenated motifs.Tetrahedron · 2013Article
- Catalyst-controlled C-O versus C-N allylic functionalization of terminal olefins.Journal of the American Chemical Society · 2013Article
- Terminal olefins to linear α,β-unsaturated ketones: Pd(II)/hypervalent iodine co-catalyzed Wacker oxidation-dehydrogenation.Journal of the American Chemical Society · 2013Article
- Transmissive olefination route to putative "morinol I" lignans.The Journal of organic chemistry · 2012Article
- Sequential allylic C-H amination/vinylic C-H arylation: a strategy for unnatural amino acid synthesis from α-olefins.Organic letters · 2012Article
- Molecular complexity via C-H activation: a dehydrogenative Diels-Alder reaction.Journal of the American Chemical Society · 2011Article
- On the macrocyclization of the erythromycin core: preorganization is not required.Angewandte Chemie (International ed. in English) · 2011Article
- Palladium catalyzed allylic C-H alkylation: a mechanistic perspective.Molecules (Basel, Switzerland) · 2011Review
- Allylic C-H acetoxylation with a 4,5-diazafluorenone-ligated palladium catalyst: a ligand-based strategy to achieve aerobic catalytic turnover.Journal of the American Chemical Society · 2010Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
A highly general, predictably selective C-H oxidation method for the direct, catalytic synthesis of complex allylic esters is introduced. This Pd(II)/sulfoxide-catalyzed method allows a wide range of complex aryl and alkyl carboxylic acids to couple directly with terminal olefins to furnish (E)-allylic esters in synthetically useful yields and selectivities (16 examples, E/Z >or= 10:1) and without the use of stoichiometric coupling reagents or unstable intermediates. Strategic advantages of constructing allylic esters via C-H oxidation vs C-C bond-forming methods are evaluated and discussed in four "case studies".
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.