ArticleThe journal of physical chemistry. C, Nanomaterials and interfaces2010
Effect of Single-Walled Carbon Nanotube Association upon H NMR Spectra of Representative Organonitrogen Compounds.
Article in The journal of physical chemistry. C, Nanomaterials and interfaces, 2010. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
2 citing papers in PubMed, 11 citations in OpenAlex.
- Biogenic synthesis and thermo-magnetic study of highly porous carbon nanotubes.IET nanobiotechnology · 2019Article
- Characterizing Covalently Sidewall-Functionalized SWCNTs by usingThe journal of physical chemistry. C, Nanomaterials and interfaces · 2013Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
This report is important to achieving SWCNT solvation, understanding adsorption of molecules on SWCNT surfaces, and SWCNT characterization by NMR. Complexation of 1-methyl-2-pyrrolidone (NMP) and other selected organonitrogens with single-walled carbon nanotubes (SWCNTs) was studied by proton nuclear magnetic resonance (NMR). The magnitude of (1)H NMR chemical shift change upon SWCNT:organonitrogen complex formation represents the strength of the association. Magnitudes of changes in NMR signals of different protons in the organonitrogen reveal which protons are in close proximity to SWCNTs. Results reveal that (1) in amides and aminoketones, SWCNT association with carbonyls is stronger than with nitrogen, (2) in aminoalcohols, SWCNT association with nitrogen is stronger than with oxygen, and (3) protons bonded to heteroatoms have greater changes in their chemical shifts than those bonded to carbons. Changes (broadening and downfield shifts) in (1)H NMR signals of the organonitrogen compounds, which accompany SWCNT:organonitrogen association, are dependent upon (1) type of proton within R (α, β, etc.), (2) proximity to the carbonyl (R-CO versus NR(2)), (3) steric effects of alkyls, (4) electronic effects of alkyls, and (5) effects of tethering two ends of a molecule.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.