ArticleCrystal growth & design2010
Charge-assisted encapsulation of two chlorides by a hexaprotonated azamacrocycle.
Article in Crystal growth & design, 2010. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
10 citing papers in PubMed.
- Study on the Photoluminescent and Thermal Properties of Zinc Complexes with a N₆O₄ Macrocyclic Ligand.Molecules (Basel, Switzerland) · 2018Article
- Article
- Remarkable hexafunctional anion receptor with operational urea-based inner cleft and thiourea-based outer cleft: Novel design with high-efficiency for sulfate binding.Scientific reports · 2017Article
- Experimental and theoretical studies on halide binding with a p-xylyl-based azamacrocycle.The journal of physical chemistry. A · 2015Article
- Encapsulation and selectivity of sulfate with a furan-based hexaazamacrocyclic receptor in water.Organic & biomolecular chemistry · 2014Article
- A highly efficient dinuclear Cu(II) chemosensor for colorimetric and fluorescent detection of cyanide in water.RSC advances · 2014Article
- Electronic Properties of Vinylene-Linked Heterocyclic Conducting Polymers: Predictive Design and Rational Guidance from DFT Calculations.The journal of physical chemistry. C, Nanomaterials and interfaces · 2011Article
- A C Symmetric Nitrate Complex with a Thiophene-Based Tripodal Receptor.Crystal growth & design · 2011Article
- Binding and selectivity aspects of an expanded azamacrocycle for anions.Inorganic chemistry communications · 2010Article
- Cooperative NH⋯O and CH⋯O interactions for sulfate encapsulation in a thiophene-based macrocycle.Tetrahedron letters · 2010Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
A chloride complex of a hexaprotonated azamacrocycle has been isolated, and its structure has been determined by X-ray crystallography showing two encapsulated chloride anions in the cavity. The two internal guests are coordinated at two binding sites on the opposite side of the macrocycle through trigonal recognition by hydrogen-bonding interactions. The other four chlorides are located outside the cavity, each with a single hydrogen bond from secondary amines. Ab initio calculations based on density functional theory (DFT) suggest that the encapsulation of two chlorides inside the cavity leads to a significant charge transfer from the anions to the protonated amines.
Identifiers
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Registered trials
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