ArticleInorganic chemistry2010
Role of the secondary coordination sphere in metal-mediated dioxygen activation.
Article in Inorganic chemistry, 2010. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 87 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
87 citing papers in PubMed, 298 citations in OpenAlex.
- Unlocking Distinct Excited States of a Nickel(II) Complex Without Modulating the Primary Coordination Sphere.JACS Au · 2026Article
- Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron.Nature chemistry · 2026Article
- Ancillary Ligand-Controlled Dinitrogen Cleavage and Transformation at Titanium Centers.Angewandte Chemie (International ed. in English) · 2026Article
- EPR spectroscopy reveals glycerol-dependent activation of cysteamine dioxygenase (ADO) enables bidentate substrate coordination.The Journal of biological chemistry · 2026Article
- A mononuclear nonheme iron complex with higher affinity for ONature communications · 2026Article
- Iron to Cobalt Swapping in a Bioinspired Heme-Peroxidase: Structural Characterization and Functional Implications.Inorganic chemistry · 2026Article
- Macromolecular and Supramolecular Organization of Ionomers.Polymers · 2025Review
- Formation of Supramolecular Structures in Oxidation Processes Catalyzed by Heteroligand Complexes of Iron and Nickel: Models of Enzymes.International journal of molecular sciences · 2025Article
- Alkali Counterion-Dependent Crystallization of Uranium(IV)-Chloro Structural Units.Inorganic chemistry · 2025Article
- Generation and Reactivity of a High-Spin Iron(IV)-Oxo Complex That Is Stable at Ambient Temperatures.Journal of the American Chemical Society · 2025Article
- Secondary Sphere Lewis Acid Activated Heme Superoxo Adducts Mimic Crucial Non-Covalent Interactions in IDO/TDO Heme Dioxygenases.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- Copper-oxygen adducts: new trends in characterization and properties towards C-H activation.Chemical science · 2024Review
- Coordination Modes and Binding Patterns in Lanthanum Phosphoramide Complexes.Inorganic chemistry · 2024Article
- Enhanced Reactivities of Iron(IV)-Oxo Porphyrin Species in Oxidation Reactions Promoted by Intramolecular Hydrogen-Bonding.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Modulation of the Bonding between Copper and a Redox-Active Ligand by Hydrogen Bonds and Its Effect on Electronic Coupling and Spin States.Journal of the American Chemical Society · 2024Article
- From Biomimicking to Bioinspired Design of Electrocatalysts for COAngewandte Chemie (International ed. in English) · 2024Review
- Mechanisms and Opportunities for Rational In Silico Design of Enzymes to Degrade Per- and Polyfluoroalkyl Substances (PFAS).Journal of chemical information and modeling · 2023Review
- The Role H-Bonding and Supramolecular Structures in Homogeneous and Enzymatic Catalysis.International journal of molecular sciences · 2023Article
- Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis.Chemical reviews · 2023Review
- Selective Metal-ion Complexation of a Biomimetic Calix[6]arene Funnel Cavity Functionalized with Phenol or Quinone.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
27 more citing papers are in PubMed but not listed here.
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
Alfred Werner proposed nearly 100 years ago that the secondary coordination sphere has a role in determining the physical properties of transition-metal complexes. We now know that the secondary coordination sphere impacts nearly all aspects of transition-metal chemistry, including the reactivity and selectivity in metal-mediated processes. These features are highlighted in the binding and activation of dioxygen by transition-metal complexes. There are clear connections between control of the secondary coordination sphere and the ability of metal complexes to (1) reversibly bind dioxygen or (2) bind and activate dioxygen to form highly reactive metal-oxo complexes. In this Forum Article, several biological and synthetic examples are presented and discussed in terms of structure-function relationships. Particular emphasis is given to systems with defined noncovalent interactions, such as intramolecular H-bonds involving dioxygen-derived ligands. To further illustrate these effects, the homolytic cleavage of C-H bonds by metal-oxo complexes with basic oxo ligands is described.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.