ArticleProceedings of the National Academy of Sciences of the United States of America2010
Effect of hydrogen bond cooperativity on the behavior of water.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2010. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 35 papers.
What it found
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Who cites it
35 citing papers in PubMed.
- Unravelling Water Anomalies Using a Percolation Approach.ACS omega · 2026Article
- Assessing Order in Liquid, Supercooled, and Crystalline Water.The journal of physical chemistry. B · 2026Article
- Ultrafast Intermolecular Dynamics of Nanoconfined Water in Swollen Lipid Cubic Mesophases.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Interfaces govern the structure of angstrom-scale confined water solutions.Nature communications · 2025Article
- Dichotomous behavior of water in binary mixtures with a turning point between 40 and 60 °C.RSC advances · 2025Article
- Water-mediated ribonucleotide-amino acid pairs and higher-order structures at the RNA-protein interface: analysis of the crystal structure database and a topological classification.NAR genomics and bioinformatics · 2024Article
- A bicarbonate-rich liquid condensed phase in non-saturated solutions in the absence of divalent cations.Frontiers in bioengineering and biotechnology · 2024Article
- Hydrophobic Homopolymer's Coil-Globule Transition and Adsorption onto a Hydrophobic Surface under Different Conditions.The journal of physical chemistry. B · 2023Article
- Understanding the influence of alkali cations and halogen anions on the cooperativity of cyclic hydrogen-bonded rosettes in supramolecular stacks.Chemistry, an Asian journal · 2022Article
- Multiple insights call for revision of modern thermodynamic models to account for structural fluctuations in water.AIChE journal. American Institute of Chemical Engineers · 2022Article
- Structural changes across thermodynamic maxima in supercooled liquid tellurium: A water-like scenario.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Anticooperativity of Multiple Halogen Bonds and Its Effect on Stoichiometry of Cocrystals of Perfluorinated Iodobenzenes.Crystal growth & design · 2022Article
- Advances in the study of supercooled water.The European physical journal. E, Soft matter · 2021Review
- Implicit water model within the Zimm-Bragg approach to analyze experimental data for heat and cold denaturation of proteins.Communications chemistry · 2021Article
- Article
- Specific Heat and Transport Functions ofWater.International journal of molecular sciences · 2020Article
- Ultrafast hydrogen bond dynamics of liquid water revealed by terahertz-induced transient birefringence.Light, science & applications · 2020Article
- The Proton Density of States in Confined Water (HInternational journal of molecular sciences · 2019Article
- Water-like anomalies as a function of tetrahedrality.Proceedings of the National Academy of Sciences of the United States of America · 2018Article
- Supercooled and glassy water: Metastable liquid(s), amorphous solid(s), and a no-man's land.Proceedings of the National Academy of Sciences of the United States of America · 2017Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Four scenarios have been proposed for the low-temperature phase behavior of liquid water, each predicting different thermodynamics. The physical mechanism that leads to each is debated. Moreover, it is still unclear which of the scenarios best describes water, because there is no definitive experimental test. Here we address both open issues within the framework of a microscopic cell model by performing a study combining mean-field calculations and Monte Carlo simulations. We show that a common physical mechanism underlies each of the four scenarios, and that two key physical quantities determine which of the four scenarios describes water: (i) the strength of the directional component of the hydrogen bond and (ii) the strength of the cooperative component of the hydrogen bond. The four scenarios may be mapped in the space of these two quantities. We argue that our conclusions are model independent. Using estimates from experimental data for H-bond properties the model predicts that the low-temperature phase diagram of water exhibits a liquid-liquid critical point at positive pressure.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.