ArticleOrganic letters2010
Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates.
Article in Organic letters, 2010. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
14 citing papers in PubMed.
- HFIP-Induced Formation ofThe Journal of organic chemistry · 2026Article
- Enantioselective Synthesis of Allylic Sulfones via Rhodium-Catalyzed Direct Hydrosulfonylation of Allenes and Alkynes.Journal of the American Chemical Society · 2024Article
- A general copper-catalysed enantioconvergent C(spNature chemistry · 2024Article
- Regiodivergent sulfonylation of terminal olefinsNew journal of chemistry = Nouveau journal de chimie · 2023Article
- Catalytic Enantioselective Entry to Triflones Featuring a Quaternary Stereocenter.Organic letters · 2022Article
- Palladium-catalyzed regioselective hydrosulfonylation of allenes with sulfinic acids.RSC advances · 2022Article
- Synthesis and applications of sodium sulfinates (RSORSC advances · 2021Review
- Regioselective molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications.Chemical science · 2020Article
- Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives through Iridium-Catalyzed Allylic Alkylation.Angewandte Chemie (International ed. in English) · 2017Article
- Copper(i)-catalyzed sulfonylative Suzuki-Miyaura cross-coupling.Chemical science · 2017Article
- Stereoconvergent arylations and alkenylations of unactivated alkyl electrophiles: catalytic enantioselective synthesis of secondary sulfonamides and sulfones.Journal of the American Chemical Society · 2014Article
- Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran.Journal of the American Chemical Society · 2012Article
- Mechanistically driven development of iridium catalysts for asymmetric allylic substitution.Accounts of chemical research · 2010Article
- Iridium-catalyzed kinetic asymmetric transformations of racemic allylic benzoates.Journal of the American Chemical Society · 2010Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
Abstract
The iridium-catalyzed allylation of sodium sulfinate to form branched allylic sulfones is reported. The reactions between various sodium sulfinates and achiral allylic carbonates occur in good yields, with high selectivity for the branched isomer, and high enantioselectivities (up to 98% ee).
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.