ArticlePolymer2008
Polymerization Behavior and Polymer Properties of Eosin-Mediated Surface Modification Reactions.
Article in Polymer, 2008. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
13 citing papers in PubMed.
- Photocrosslinkable natural polymers in tissue engineering.Frontiers in bioengineering and biotechnology · 2023Review
- Surface-Immobilized Photoinitiators for Light Induced Polymerization and Coupling Reactions.Polymers · 2022Review
- Water-Soluble Photoinitiators in Biomedical Applications.Polymers · 2020Review
- Comparison of eosin and fluorescein conjugates for the photoinitiation of cell-compatible polymer coatings.PloS one · 2018Article
- Hydrogel Patches on Live Cells through Surface-Mediated Polymerization.Langmuir : the ACS journal of surfaces and colloids · 2017Article
- The Role of Surface Receptor Density in Surface-Initiated Polymerizations for Cancer Cell Isolation.Langmuir : the ACS journal of surfaces and colloids · 2016Article
- Characterization of molecular transport in ultrathin hydrogel coatings for cellular immunoprotection.Biomacromolecules · 2015Article
- PEG molecular net-cloth grafted on polymeric substrates and its bio-merits.Scientific reports · 2014Article
- Glucose oxidase-mediated polymerization as a platform for dual-mode signal amplification and biodetection.Biotechnology and bioengineering · 2011Article
- Sensitive immunofluorescent staining of cells via generation of fluorescent nanoscale polymer films in response to biorecognition.The journal of histochemistry and cytochemistry : official journal of the Histochemistry Society · 2011Article
- Photoinitiator nucleotide for quantifying nucleic Acid hybridization.Biomacromolecules · 2010Article
- Development of fluorescent polymerization-based signal amplification for sensitive and non-enzymatic biodetection in antibody microarrays.Acta biomaterialia · 2010Article
- Mechanism of Cyclic Dye Regeneration During Eosin-Sensitized Photoinitiation in the Presence of Polymerization Inhibitors.Journal of polymer science. Part A, Polymer chemistry · 2009Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Surface modification by surface-mediated polymerization necessitates control of the grafted polymer film thicknesses to achieve the desired property changes. Here, a microarray format is used to assess a range of reaction conditions and formulations rapidly in regards to the film thicknesses achieved and the polymerization behavior. Monomer formulations initiated by eosin conjugates with varying concentrations of poly(ethylene glycol) diacrylate (PEGDA), N-methyldiethanolamine (MDEA), and 1-vinyl-2-pyrrolidone (VP) were evaluated. Acrylamide with MDEA or ascorbic acid as a coinitiator was also investigated. The best formulation was found to be 40 wt% acrylamide with MDEA which yielded four to eight fold thicker films (maximum polymer thickness increased from 180 nm to 1420 nm) and generated visible films from 5-fold lower eosin surface densities (2.8 vs. 14 eosins/µm(2)) compared to a corresponding PEGDA formulation. Using a microarray format to assess multiple initiator surface densities enabled facile identification of a monomer formulation that yields the desired polymer properties and polymerization behavior across the requisite range of initiator surface densities.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.