ArticleJournal of the American Society for Mass Spectrometry2009
Microhydration of protonated nucleic acid bases and protonated nucleosides in the gas phase.
Article in Journal of the American Society for Mass Spectrometry, 2009. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
2 citing papers in PubMed.
- Microhydration of Deprotonated Nucleobases.Journal of the American Society for Mass Spectrometry · 2016Article
- Hydration energies of protonated and sodiated thiouracils.Journal of the American Society for Mass Spectrometry · 2014Article
Corrections and comments
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Authors and funding
1 author.
Funding
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Abstract
Thermochemical data, DeltaH(o)(n), DeltaS(o)(n), and DeltaG(o)(n), for the hydration of protonated nucleic acid bases and protonated nucleosides have been experimentally studied by equilibrium measurements using an electrospray high-pressure mass spectrometer equipped with a pulsed ion-beam reaction chamber. For protonated nucleobases the hydration enthalpies were found to be similar for all studied systems and varied between 12.4-13.1 kcal/mol for the first and 11.2-11.5 kcal/mol for the second water molecule. While for protonated nucleosides the water binding enthalpies (11.7-13.3 kcal/mol) are very close to those for protonated nucleobases, the entropy values are "more negative." The structural and energetic aspects of hydrated ions are discussed in conjunction with the available theoretical data.
Indexed as
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Registered trials
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