ArticleJournal of the American Chemical Society2009
A catalytic, Brønsted base strategy for intermolecular allylic C-H amination.
Article in Journal of the American Chemical Society, 2009. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 32 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
32 citing papers in PubMed.
- C(spJournal of the American Chemical Society · 2025Article
- Allylic C-H oxygenation of unactivated internal olefins by the Cu/azodiformate catalyst system.Nature communications · 2025Article
- Halide Perovskite Induces Halogen/Hydrogen Atom Transfer (XAT/HAT) for Allylic C-H Amination.Angewandte Chemie (International ed. in English) · 2025Article
- Synthesis of Borylated Carbocycles by [2 + 2]-Cycloadditions and Photo-Ene Reactions.Journal of the American Chemical Society · 2024Article
- Direct synthesis of branched amines enabled by dual-catalyzed allylic C─H amination of alkenes with amines.Science advances · 2024Article
- Article
- Biocatalytic Transamination of Aldolase-Derived 3-Hydroxy Ketones.Advanced synthesis & catalysis · 2023Article
- Asymmetric intermolecular allylic C-H amination of alkenes with aliphatic amines.Science (New York, N.Y.) · 2022Article
- SulfoxFluor-enabled deoxyazidation of alcohols with NaNNature communications · 2022Article
- C-H Activation: Toward Sustainability and Applications.ACS central science · 2021Review
- Intermolecular oxidative amination of unactivated alkenes by dual photoredox and copper catalysis.Chemical science · 2020Article
- Ir-Catalyzed Intermolecular Branch-Selective Allylic C-H Amidation of Unactivated Terminal Olefins.Journal of the American Chemical Society · 2019Article
- C-H to C-N Cross-Coupling of Sulfonamides with Olefins.Journal of the American Chemical Society · 2018Article
- Aerobic Linear Allylic C-H Amination: Overcoming Benzoquinone Inhibition.Journal of the American Chemical Society · 2016Article
- A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp(3))-H amination.Nature chemistry · 2015Article
- Tuning the Reactivity of Radical through a Triplet Diradical Cu(II) Intermediate in Radical Oxidative Cross-Coupling.Scientific reports · 2015Article
- Terminal olefins to chromans, isochromans, and pyrans via allylic C-H oxidation.Journal of the American Chemical Society · 2014Article
- N-Boc amines to oxazolidinones via Pd(II)/bis-sulfoxide/Brønsted acid co-catalyzed allylic C-H oxidation.Journal of the American Chemical Society · 2014Article
- Chemo- and regioselective C(sp³)-H arylation of unactivated allylarenes by deprotonative cross-coupling.Angewandte Chemie (International ed. in English) · 2014Article
- A C-H oxidation approach for streamlining synthesis of chiral polyoxygenated motifs.Tetrahedron · 2013Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
Abstract
A Brønsted base activation mode for oxidative, Pd(II)/sulfoxide-catalyzed, intermolecular C-H allylic amination is reported. N,N-diisopropylethylamine was found to promote amination of unactivated terminal olefins, forming the corresponding linear allylic amine products with high levels of stereo-, regio-, and chemoselectivity. The predictable and high selectivity of this C-H oxidation method enables late-stage incorporation of nitrogen into advanced synthetic intermediates and natural products.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.