ArticleThe European physical journal. E, Soft matter2009
Correlation effects, image charge effects and finite size in the macro-ion-electrolyte system: a field-theoretic approach.
Article in The European physical journal. E, Soft matter, 2009. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
0 citing papers in PubMed.
No citing paper in PubMed yet.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
1 author.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We consider a model of a macro-ion surrounded by small ions of an electrolyte solution. The finite size of ionic charge distributions of ions, and image charge effects are considered. From such a model it is possible to construct a statistical field theory with a single fluctuating field and derive physical interpretations for both the mean field and two-point correlation function. For point-like charges, at the level of a Gaussian (or saddle point) approximation, we recover the standard Poisson-Boltzmann equation. However, to include ionic correlation effects, as well as image charge effects of individual ions, we must go beyond this. From the field theory considered, it is possible to construct self-consistent approximations. We consider the simplest of these, namely the Hartree approximation. The Hartree equations take the form of two coupled equations. One is a modified Poisson-Boltzmann equation; the other describes both image charge effects on the individual ions, as well as correlations. Such equations are difficult to solve numerically, so we develop an (a WKB-like) approximation for obtaining approximate solutions. This, we apply to a uniformly charged rod in univalent electrolyte solution, for point like ions, as well as for extended spherically symmetric distributions of ionic charge on electrolyte ions. The solutions show how correlation effects and image charge effects modify the Poisson-Boltzmann result. Finite-size charge distributions of the ions reduce both the effects of correlations and image charge effects. For point charges, we test the WKB approximation by calculating a leading-order correction from the exact Hartree result, showing that the WKB-like approximation works reasonably well in describing the full solution to the Hartree equations. From these solutions, we also calculate an effective charge compensation parameter in an analytical formula for the interaction of two charged cylinders.
Indexed as
Identifiers
19408022What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.