ArticleBiochemistry2009
Biomimetic chemistry of iron, nickel, molybdenum, and tungsten in sulfur-ligated protein sites.
Article in Biochemistry, 2009. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
19 citing papers in PubMed.
- Hangman dipyrrin complexes.Chemical science · 2026Article
- Nickel model complexes to mimic carbon monoxide dehydrogenase reactions.Chemical science · 2025Review
- Synthetic Challenges toward Modeling Formate Dehydrogenases Using [WInorganic chemistry · 2024Article
- Quantum Mimicry With Inorganic Chemistry.Comments on modern chemistry. Part A, Comments on inorganic chemistry : a journal of critical discussion of the current literature · 2024Article
- Isolation of a Homoleptic Non-oxo Mo(V) Alkoxide Complex: Synthesis, Structure, and Electronic Properties of Penta-Journal of the American Chemical Society · 2020Article
- A W/Cu Synthetic Model for the Mo/Cu Cofactor of Aerobic CODH Indicates That Biochemical CO Oxidation Requires a Frustrated Lewis Acid/Base Pair.Journal of the American Chemical Society · 2020Article
- Dioxygen Activation with Molybdenum Complexes Bearing Amide-Functionalized Iminophenolate Ligands.Molecules (Basel, Switzerland) · 2019Article
- Ultrafast Photodynamics of Cyano-Functionalized [FeFe] Hydrogenase Model Compounds.The journal of physical chemistry. A · 2018Article
- Photochemical Dynamics of a Trimethyl-Phosphine Derivatized [FeFe]-Hydrogenase Model Compound.Chemical physics · 2018Article
- Using solution- and solid-state S K-edge X-ray absorption spectroscopy with density functional theory to evaluate M-S bonding for MS4(2-) (M = Cr, Mo, W) dianions.Dalton transactions (Cambridge, England : 2003) · 2014Article
- Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clusters.Chemical reviews · 2014Review
- Early bioenergetic evolution.Philosophical transactions of the Royal Society of London. Series B, Biological sciences · 2013Review
- Metal centers in the anaerobic microbial metabolism of CO and CO2.Metallomics : integrated biometal science · 2011Review
- The [MoFe3S4]2+ oxidation state: synthesis, substitution reactions, and structures of phosphine-ligated cubane-type clusters with the S=2 ground state.Inorganic chemistry · 2011Article
- NifEN-B complex of Azotobacter vinelandii is fully functional in nitrogenase FeMo cofactor assembly.Proceedings of the National Academy of Sciences of the United States of America · 2011Article
- Biosynthesis of Nitrogenase FeMoco.Coordination chemistry reviews · 2011Article
- From thioxo cluster to dithio cluster: exploring the chemistry of polynuclear zirconium complexes with S,O and S,S ligands.Inorganic chemistry · 2011Article
- Reactions of the terminal Ni(II)-OH group in substitution and electrophilic reactions with carbon dioxide and other substrates: structural definition of binding modes in an intramolecular Ni(II)...Fe(II) bridged site.Journal of the American Chemical Society · 2010Article
- Molybdenum cofactors, enzymes and pathways.Nature · 2009Review
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Biomimetic inorganic chemistry has as its primary goal the synthesis of molecules that approach or achieve the structures, oxidation states, and electronic and reactivity features of native metal-containing sites of variant nuclearity. Comparison of properties of accurate analogues and these sites ideally provides insight into the influence of protein structure and environment on intrinsic properties as represented by the analogue. For polynuclear sites in particular, the goal provides a formidable challenge for, with the exception of iron-sulfur clusters, all such site structures have never been achieved and few have even been closely approximated by chemical synthesis. This account describes the current status of the synthetic analogue approach as applied to the mononuclear sites in certain molybdoenzymes and the polynuclear sites in hydrogenases, nitrogenase, and carbon monoxide dehydrogenases.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.