ArticleInorganica chimica acta2007
Homogenous Water Oxidation by a Di-μ-Oxo Dimanganese Complex in the Presence of Ce.
Article in Inorganica chimica acta, 2007. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Ultra-small and highly dispersive iron oxide hydroxide as an efficient catalyst for oxidation reactions: a Swiss-army-knife catalyst.Scientific reports · 2021Article
- The role of dynamic ligand exchange in the oxidation chemistry of cerium(iii).Chemical science · 2016Article
- Photocatalytic Water Oxidation Using Manganese Compounds Immobilized in Nafion Polymer Membranes.Australian journal of chemistry · 2011Article
- [(H2O)(terpy)Mn(mu-O)2Mn(terpy)(OH2)](NO3)3 (terpy = 2,2':6,2''-terpyridine) and its relevance to the oxygen-evolving complex of photosystem II examined through pH dependent cyclic voltammetry.Dalton transactions (Cambridge, England : 2003) · 2010Article
- Functional Models for the Oxygen-Evolving Complex of Photosystem II.Coordination chemistry reviews · 2008Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
O(2) evolution was observed upon mixing aqueous [(terpy)(H(2)O)Mn(O)(2)Mn(H(2)O)(terpy)](NO(3))(3) (1, terpy = 2,2':6',6″-terpyridine) with aqueous solutions of Ce(4+). However, when the solution of 1 was incubated at pH = 1 (by dissolving in dilute HNO(3)) before mixing with Ce(4+), very small amounts of O(2) were observed. This observation of acid-induced deactivation suggests an explanation, both for the previously reported lack of O(2) evolution from aqueous solutions of 1 with Ce(4+) as oxidant, and the present observation of low amounts of O(2) production with the very acidic Ce(4+) reagent. Evidence is provided for water being the source of evolved O(2), and for the requirement of a high valent multinuclear Mn species for O(2) evolution. We test the possibility of complications in the use of cerium ammonium nitrate (CAN) in oxidation chemistry due to the presence of the oxidizable NH(4) (+) ion.
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