ArticleLipids2008
Hydroxy radical, hexanal, and decadienal generation by autocatalysts in autoxidation of linoleate alone and with eleostearate.
Article in Lipids, 2008. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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Who cites it
3 citing papers in PubMed.
- A Comparison of Different Tissues Identifies the Main Precursors of Volatile Substances in Chicken Meat.Frontiers in physiology · 2022Article
- Ferroptotic cell death triggered by conjugated linolenic acids is mediated by ACSL1.Nature communications · 2021Article
- CYP1A1 induction in the colon by serum: involvement of the PPARα pathway and evidence for a new specific human PPREα site.PloS one · 2011Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The formation of hydroxy radicals, hexanal, and 2,4-decadienal was demonstrated from the autocatalytic dimer peroxide which had been reported by us in autoxidizing linoleate (Morita and Tokita in Lipids 41:91-95, 2006). Then, autoxidizing linoleate containing eleostearate was investigated for new autocatalytic substances. The substances obtained were identified as peroxide-linked polymers consisting of both linoleate- and eleostearate-origin units with one hydroperoxy group, and also revealed activity of hydroxy-radical generation. The background of this study is as follows: the above paper reported this autocatalytic dimer peroxide as one of the real radical generators in linoleate autoxidation; this is a peroxide-linked dimer consisting of two linoleate moieties with two hydroperoxy groups, and was much more important than the main-product hydroperoxide in autocatalytic radical supply; its proposed decomposition mechanism has suggested the generation of hydroxy radicals, hexanal, and 2,4-decadienal; on the other hand, analogy to the formation mechanism of this dimer peroxide has predicted the formation of similar polymeric products from conjugated polyene components in lipids. In this study, these two predictions were successfully verified and a discussion is presented in connection with them.
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Registered trials
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