ArticleJournal of the American Society for Mass Spectrometry2008
Quadrupole excitation of ions in linear quadrupole ion traps with added octopole fields.
Article in Journal of the American Society for Mass Spectrometry, 2008. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Simulation of Unidirectional Ion Ejection in Miniature Four-Channel Linear Ion Trap Array.Sensors (Basel, Switzerland) · 2025Article
- Theoretical Study of Dual-Direction Dipolar Excitation of Ions in Linear Ion Traps.Journal of the American Society for Mass Spectrometry · 2016Article
- Nonlinear Ion Harmonics in the Paul Trap with Added Octopole Field: Theoretical Characterization and New Insight into Nonlinear Resonance Effect.Journal of the American Society for Mass Spectrometry · 2016Article
- A Theoretical Method for Characterizing Nonlinear Effects in Paul Traps with Added Octopole Field.Journal of the American Society for Mass Spectrometry · 2015Article
- Nonlinear effects in Paul traps operated in the second stability region: analytical analysis and numerical verification.Journal of the American Society for Mass Spectrometry · 2014Article
- Space charge induced nonlinear effects in quadrupole ion traps.Journal of the American Society for Mass Spectrometry · 2014Article
- Mass analysis with islands of stability with linear quadrupoles incorporating higher order multipole fields.Journal of the American Society for Mass Spectrometry · 2010Article
- Ion trap mass analysis at high pressure: a theoretical view.Journal of the American Society for Mass Spectrometry · 2009Article
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Authors and funding
3 authors.
Funding
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Abstract
Modeling and experimental studies of quadrupole excitation of ions in linear quadrupole traps with added octopole fields are described. An approximate solution to the equations of motion of ions trapped in a quadrupole with added octopole and dodecapole fields, with quadrupole excitation and damping is given. The solutions give the steady-state or stationary amplitudes of oscillation with different excitation frequencies. Trajectory calculations of the oscillation amplitudes are also presented. The calculations show that there can be large changes in the amplitude of ion oscillation with small changes in excitation frequency, on both the low and high-frequency sides of a resonance. Results of experiments with quadrupole excitation of reserpine ions in linear quadrupole traps with 2.0%, 2.6%, and 4.0% added octopole fields are given. It is found that as the excitation frequency is changed, two resonances are generally observed, which are attributed to the motion in the x and y directions. The two resonances can have quite different intensities. Sudden jumps or sharp sided resonances are not observed, although in some cases asymmetric resonances are seen. The calculated frequency differences between the two resonances are in approximate agreement with the experiments.
Identifiers
18258453What OpenQuestion holds
Registered trials
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