ArticleThe Journal of organic chemistry2007
Synthesis of branched Man5 oligosaccharides and an unusual stereochemical observation.
Article in The Journal of organic chemistry, 2007. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
8 citing papers in PubMed.
- Orthogonal protection of saccharide polyols through solvent-free one-pot sequences based on regioselective silylations.Beilstein journal of organic chemistry · 2016Article
- Chemoenzymatic synthesis of α-dystroglycan core M1 O-mannose glycans.Chemical communications (Cambridge, England) · 2015Article
- Pre-activation based stereoselective glycosylations: Stereochemical control by additives and solvent.Science China. Chemistry · 2011Article
- Preactivation-based, one-pot combinatorial synthesis of heparin-like hexasaccharides for the analysis of heparin-protein interactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2010Article
- Fluorous-Assisted One-Pot Oligosaccharide Synthesis.European journal of organic chemistry · 2010Article
- Installation of electron-donating protective groups, a strategy for glycosylating unreactive thioglycosyl acceptors using the preactivation-based glycosylation method.The Journal of organic chemistry · 2008Article
- Chemoenzymatic Syntheses of Tumor-Associated Carbohydrate Antigen Globo-H and Stage-Specific Embryonic Antigen 4.Advanced synthesis & catalysis · 2008Article
- Pre-activation-based one-pot synthesis of an alpha-(2,3)-sialylated core-fucosylated complex type bi-antennary N-glycan dodecasaccharide.Chemistry (Weinheim an der Bergstrasse, Germany) · 2008Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Branched mannopentaoses were synthesized through two routes. While assembly from the nonreducing end to the reducing end was more convergent with fewer intermediate steps, two diastereomers were obtained. On the other hand, synthesis from the reducing end to the nonreducing end yielded the mannopentaose with the desired stereochemistry as a single isomer. Our results suggest that it is still challenging to reliably predict stereochemical outcome of a glycosylation reaction. It is necessary to thoroughly characterize anomeric configurations of newly formed glycosidic linkages in complex oligosaccharide synthesis.
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Registered trials
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