ArticleThe Journal of organic chemistry2005
Synthesis and luminescence of soluble meso-unsubstituted tetrabenzo- and tetranaphtho[2,3]porphyrins.
Article in The Journal of organic chemistry, 2005. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
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Who cites it
23 citing papers in PubMed.
- Synthesis of NovelACS omega · 2025Article
- From (Sub)Porphyrins to (Sub)Phthalocyanines: Aromaticity Signatures in the UV-Vis Absorption Spectra.Inorganic chemistry · 2024Article
- SynergisticChemical science · 2024Article
- Article
- Hypoxia-active nanoparticles used in tumor theranostic.International journal of nanomedicine · 2019Review
- Two-Photon Absorbing Phosphorescent Metalloporphyrins: Effects of π-Extension and Peripheral Substitution.Journal of the American Chemical Society · 2016Article
- Bright, "Clickable" Porphyrins for the Visualization of Oxygenation under Ambient Light.Angewandte Chemie (International ed. in English) · 2015Article
- A Phosphorescent Iridium(III) Complex-Modified Nanoprobe for Hypoxia Bioimaging Via Time-Resolved Luminescence Microscopy.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2015Article
- Synthesis of phosphorescent asymmetrically π-extended porphyrins for two-photon applications.The Journal of organic chemistry · 2014Article
- Two-photon antenna-core oxygen probe with enhanced performance.Analytical chemistry · 2014Article
- Magnetic Field Effects on Triplet-Triplet Annihilation in Solutions: Modulation of Visible/NIR Luminescence.The journal of physical chemistry letters · 2013Article
- Tuning the dynamic range and sensitivity of optical oxygen-sensors by employing differently substituted polystyrene-derivatives.Sensors and actuators. B, Chemical · 2013Article
- Indicators for optical oxygen sensors.Bioanalytical reviews · 2012Article
- Stable optical oxygen sensing materials based on click-coupling of fluorinated platinum(II) and palladium(II) porphyrins-A convenient way to eliminate dye migration and leaching.Sensors and actuators. B, Chemical · 2012Article
- Optical probes and techniques for O2 measurement in live cells and tissue.Cellular and molecular life sciences : CMLS · 2012Review
- Two new "protected" oxyphors for biological oximetry: properties and application in tumor imaging.Analytical chemistry · 2011Article
- Strongly Phosphorescent Iridium(III)-Porphyrins - New Oxygen Indicators with Tuneable Photophysical Properties and Functionalities.European journal of inorganic chemistry · 2011Article
- Phosphorescent platinum(II) and palladium(II) complexes with azatetrabenzoporphyrins-new red laser diode-compatible indicators for optical oxygen sensing.ACS applied materials & interfaces · 2010Article
- Dendritic phosphorescent probes for oxygen imaging in biological systems.ACS applied materials & interfaces · 2009Article
- Effects of structural deformations on optical properties of tetrabenzoporphyrins: free-bases and Pd complexes.The journal of physical chemistry. A · 2008Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
[Structure: see text]. Syntheses of soluble tetrabenzoporphyrins (TBP) and tetranaphtho[2,3]porphyrins (TNP), with multiple substituents in the conjugated aromatic rings but bearing no substituents in the meso-positions, is reported. Both types of porphyrins were obtained by direct aromatization of precursor porphyrins, annealed with either cyclohexene or dihydronaphthalene fragments. TBPs and TNPs possess powerful absorption bands in the near-infrared (lambda = 610-710 nm, epsilon = 100,000-300,000 M(-1) cm(-1)) and exhibit strong luminescence. Free bases and Zn complexes fluoresce with quantum yields of up to 50%, whereas Pd and Pt complexes phosphoresce in solutions at ambient temperatures. Remarkably, the phosphorescence quantum yields of Pd and Pt TBPs reach as high as 20-50%, which places them among the brightest near-infrared phosphors known to date.
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