ArticleJournal of the American Society for Mass Spectrometry2002
Evidence for long-range glycosyl transfer reactions in the gas phase.
Article in Journal of the American Society for Mass Spectrometry, 2002. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed, 58 citations in OpenAlex.
- Collision-Induced Fragmentation of Oligosaccharides: Mechanistic Insights for Mass Spectrometry-Based Glycomics.Angewandte Chemie (International ed. in English) · 2025Review
- Mass Spectrometry-Based Techniques to Elucidate the Sugar Code.Chemical reviews · 2022Review
- New strategies for profiling and characterization of human milk oligosaccharides.Glycobiology · 2020Article
- The role of the mobile proton in fucose migration.Analytical and bioanalytical chemistry · 2019Article
- Characterization of Isomeric Glycans by Reversed Phase Liquid Chromatography-Electronic Excitation Dissociation Tandem Mass Spectrometry.Journal of the American Society for Mass Spectrometry · 2018Article
- Xylose Migration During Tandem Mass Spectrometry of N-Linked Glycans.Journal of the American Society for Mass Spectrometry · 2017Article
- A Method for In-Depth Structural Annotation of Human Serum Glycans That Yields Biological Variations.Analytical chemistry · 2015Article
- Mass spectrometry of glycans.Biochemistry. Biokhimiia · 2013Review
- Isomer-specific LC/MS and LC/MS/MS profiling of the mouse serum N-glycome revealing a number of novel sialylated N-glycans.Analytical chemistry · 2013Article
- Structural Characterization of Carbohydrates by Fourier Transform Tandem Mass Spectrometry.Current proteomics · 2011Article
- Annotation and structural analysis of sialylated human milk oligosaccharides.Journal of proteome research · 2011Article
- Using non-covalent complexes to direct the fragmentation of glycosidic bonds in the gas phase.Journal of the American Society for Mass Spectrometry · 2004Article
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A long-range glycosyl transfer reaction was observed in the collision-induced dissociation Fourier transform (CID FT) mass spectra of benzylamine-labeled and 9-aminofluorene-labeled lacto-N-fucopentaose I (LNFP I) and lacto-N-difucohexaose I (LNDFH I). The transfer reaction was observed for the protonated molecules but not for the sodiated molecules. The long-range glycosyl transfer reaction involved preferentially one of the two L-fucose units in labeled LNDFH I. CID experiments with labeled LNFP I and labeled LNFP II determined the fucose with the greatest propensity for migration. Further experiments were performed to determine the final destination of the migrating fucose. Molecular modeling supported the experiments and reaction mechanisms are proposed.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.